Current distributions already contain the most needed IPv6 enabled client and servers. See first on IPv6+Linux-Status-Distribution. If still not included, you can check IPv6 & Linux - Current Status - Applications whether the program is already ported to IPv6 and usable with Linux. For common used programs there are some hints available at IPv6 & Linux - HowTo - Part 3 and IPv6 & Linux - HowTo - Part 4.
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